Remove Duplicate From String Algorithm

This led to its widespread purpose, for example in gzip compressed files and PNG picture files, in addition to the ZIP file format for which Katz originally designed it. Inc. As stated in the RFC document, an algorithm produce Deflate files was widely thought to be implementable in a manner not covered by patents.
package Others;

import java.io.BufferedReader;
import java.io.InputStreamReader;

/**
 * @author Varun Upadhyay (https://github.com/varunu28)
 */

public class RemoveDuplicateFromString {
    public static void main(String[] args) throws Exception {
        BufferedReader br = new BufferedReader(new InputStreamReader(System.in));
        String inpStr = br.readLine();

        System.out.println("Actual string is: " + inpStr);
        System.out.println("String after removing duplicates: " + removeDuplicate(inpStr));

        br.close();
    }

    /**
     * This method produces a string after removing all the duplicate characters from input string and returns it
     * Example: Input String - "aabbbccccddddd"
     * Output String - "abcd"
     *
     * @param s String from which duplicate characters have to be removed
     * @return string with only unique characters
     */

    public static String removeDuplicate(String s) {
        if (s == null || s.isEmpty()) {
            return s;
        }

        StringBuilder sb = new StringBuilder();
        int n = s.length();

        for (int i = 0; i < n; i++) {
            if (sb.toString().indexOf(s.charAt(i)) == -1) {
                sb.append(String.valueOf(s.charAt(i)));
            }
        }

        return sb.toString();
    }
}

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